Wide- and narrow-rim functionalised calix[4]arenes: synthesis and characterisation

Bernadette S. Creaven; Tammy L. Gernon; John McGinley; Ann Marie Moore; Hans Toftlund

doi:10.1016/j.tet.2006.06.096

Wide- and narrow-rim functionalised calix[4]arenes: synthesis and characterisation

Bernadette S. Creaven, Tammy L. Gernon, John McGinley, Ann Marie Moore, Hans Toftlund

Research output: Contribution to journal › Article › peer-review

Abstract

Functionalisation of calix[4]arene at both the wide and narrow rims leads to the formation of compounds containing bipyridyl, via an amide linkage, at the wide rim and having either a butyl chain, a benzyl group or an alkyl ester functionality at the narrow rim. All compounds were characterised using ¹H and ¹³C NMR spectroscopies. Initial binding studies with Ru(bipy)₂Cl₂ are reported.

Original language	English
Pages (from-to)	9066-9071
Number of pages	6
Journal	Tetrahedron
Volume	62
Issue number	38
DOIs	https://doi.org/10.1016/j.tet.2006.06.096
Publication status	Published - 18 Sep 2006

Keywords

Amide linkage
Calix[4]arene
Functionalisation
NMR
Synthesis

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10.1016/j.tet.2006.06.096

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title = "Wide- and narrow-rim functionalised calix[4]arenes: synthesis and characterisation",

abstract = "Functionalisation of calix[4]arene at both the wide and narrow rims leads to the formation of compounds containing bipyridyl, via an amide linkage, at the wide rim and having either a butyl chain, a benzyl group or an alkyl ester functionality at the narrow rim. All compounds were characterised using 1H and 13C NMR spectroscopies. Initial binding studies with Ru(bipy)2Cl2 are reported.",

keywords = "Amide linkage, Calix[4]arene, Functionalisation, NMR, Synthesis",

author = "Creaven, \{Bernadette S.\} and Gernon, \{Tammy L.\} and John McGinley and Moore, \{Ann Marie\} and Hans Toftlund",

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T1 - Wide- and narrow-rim functionalised calix[4]arenes

T2 - synthesis and characterisation

AU - Creaven, Bernadette S.

AU - Gernon, Tammy L.

AU - McGinley, John

AU - Moore, Ann Marie

AU - Toftlund, Hans

PY - 2006/9/18

Y1 - 2006/9/18

N2 - Functionalisation of calix[4]arene at both the wide and narrow rims leads to the formation of compounds containing bipyridyl, via an amide linkage, at the wide rim and having either a butyl chain, a benzyl group or an alkyl ester functionality at the narrow rim. All compounds were characterised using 1H and 13C NMR spectroscopies. Initial binding studies with Ru(bipy)2Cl2 are reported.

AB - Functionalisation of calix[4]arene at both the wide and narrow rims leads to the formation of compounds containing bipyridyl, via an amide linkage, at the wide rim and having either a butyl chain, a benzyl group or an alkyl ester functionality at the narrow rim. All compounds were characterised using 1H and 13C NMR spectroscopies. Initial binding studies with Ru(bipy)2Cl2 are reported.

KW - Amide linkage

KW - Calix[4]arene

KW - Functionalisation

KW - NMR

KW - Synthesis

UR - https://www.scopus.com/pages/publications/33746847680

U2 - 10.1016/j.tet.2006.06.096

DO - 10.1016/j.tet.2006.06.096

M3 - Article

AN - SCOPUS:33746847680

SN - 0040-4020

VL - 62

SP - 9066

EP - 9071

JO - Tetrahedron

JF - Tetrahedron

IS - 38

ER -

Wide- and narrow-rim functionalised calix[4]arenes: synthesis and characterisation

Abstract

Keywords

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