TY - JOUR
T1 - Tetraaryltetraanthra[2,3]porphyrins
T2 - Synthesis, structure, and optical properties
AU - Filatov, Mikhail A.
AU - Baluschev, Stanislav
AU - Ilieva, Iliyana Z.
AU - Enkelmann, Volker
AU - Miteva, Tzenka
AU - Landfester, Katharina
AU - Aleshchenkov, Sergey E.
AU - Cheprakov, Andrei V.
PY - 2012/12/21
Y1 - 2012/12/21
N2 - A synthetic route to symmetrical tetraaryltetraanthra[2,3]porphyrins (Ar4TAPs) was developed. Ar4TAPs bearing various substituents in meso-phenyls and anthracene residues were prepared from the corresponding pyrrolic precursors. The synthesized porphyrins possess high solubility and exhibit remarkably strong absorption bands in the near-infrared region (790-950 nm). The scope of the method, selection of the peripheral substituents, choice of the metal, and their influence on the optical properties are discussed together with the first X-ray crystallographic data for anthraporphyrin.
AB - A synthetic route to symmetrical tetraaryltetraanthra[2,3]porphyrins (Ar4TAPs) was developed. Ar4TAPs bearing various substituents in meso-phenyls and anthracene residues were prepared from the corresponding pyrrolic precursors. The synthesized porphyrins possess high solubility and exhibit remarkably strong absorption bands in the near-infrared region (790-950 nm). The scope of the method, selection of the peripheral substituents, choice of the metal, and their influence on the optical properties are discussed together with the first X-ray crystallographic data for anthraporphyrin.
UR - https://www.scopus.com/pages/publications/84871531183
U2 - 10.1021/jo302135q
DO - 10.1021/jo302135q
M3 - Article
AN - SCOPUS:84871531183
SN - 0022-3263
VL - 77
SP - 11119
EP - 11131
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 24
ER -