Synthesis and catalase activity of manganese(II) complexes of cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH2): X-ray crystal structure of [Mn(η1η1-nda)(phen)2]·EtOH·H2O (phen = 1,10-phenantholine)

Michael Devereux; Martin Curran; Malachy McCann; Michael T. Casey; Vickie McKee; Vickie McKee

doi:10.1016/0277-5387(94)00492-W

Synthesis and catalase activity of manganese(II) complexes of cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH₂): X-ray crystal structure of [Mn(η¹η¹-nda)(phen)₂]·EtOH·H₂O (phen = 1,10-phenantholine)

Michael Devereux
, Martin Curran
, Malachy McCann
, Michael T. Casey
, Vickie McKee
, Vickie McKee

VP Research and Innovation

Research output: Contribution to journal › Article › peer-review

Abstract

Manganese(II) chloride reacts with the sodium salt of cis-5-norbornene-endo-2,3-dicarboxylix acid (ndaH₂) in aqueous media to give the manganese(II) complex [Mn (nda)H₂O] (1). Complex 1 reacts with 1,10-phenanthroline (phen) to give the mononuclear manganese(II) adduct [Mn(η¹η¹-nda)(phen)₂]·EtOH·H₂O (2). The X-ray crystal structure of 2 shows the manganese atom at the centre of a distorted N₄O₂ octahedron comprising four nitrogen atoms from two chelating phen ligands, and two oxygen atoms, one from each of the two carbohylate functions of the nda^-2 ligand. Spectroscopic and magnetic data for 1 and 2 are reported, together with their catalytic activity towards the disproportionation of H₂O₂.

Original language	English
Pages (from-to)	2247-2253
Number of pages	7
Journal	Polyhedron
Volume	14
Issue number	15-16
DOIs	https://doi.org/10.1016/0277-5387(94)00492-W
Publication status	Published - Aug 1995

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@article{1baba234e78d4c40ab93f9ab9f96d328,

title = "Synthesis and catalase activity of manganese(II) complexes of cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH2): X-ray crystal structure of [Mn(η1η1-nda)(phen)2]·EtOH·H2O (phen = 1,10-phenantholine)",

abstract = "Manganese(II) chloride reacts with the sodium salt of cis-5-norbornene-endo-2,3-dicarboxylix acid (ndaH2) in aqueous media to give the manganese(II) complex [Mn (nda)H2O] (1). Complex 1 reacts with 1,10-phenanthroline (phen) to give the mononuclear manganese(II) adduct [Mn(η1η1-nda)(phen)2]·EtOH·H2O (2). The X-ray crystal structure of 2 shows the manganese atom at the centre of a distorted N4O2 octahedron comprising four nitrogen atoms from two chelating phen ligands, and two oxygen atoms, one from each of the two carbohylate functions of the nda-2 ligand. Spectroscopic and magnetic data for 1 and 2 are reported, together with their catalytic activity towards the disproportionation of H2O2.",

author = "Michael Devereux and Martin Curran and Malachy McCann and Casey, \{Michael T.\} and Vickie McKee and Vickie McKee",

year = "1995",

month = aug,

doi = "10.1016/0277-5387(94)00492-W",

language = "English",

volume = "14",

pages = "2247--2253",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "15-16",

}

Devereux, M, Curran, M, McCann, M, Casey, MT, McKee, V & McKee, V 1995, 'Synthesis and catalase activity of manganese(II) complexes of cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH₂): X-ray crystal structure of [Mn(η¹η¹-nda)(phen)₂]·EtOH·H₂O (phen = 1,10-phenantholine)', Polyhedron, vol. 14, no. 15-16, pp. 2247-2253. https://doi.org/10.1016/0277-5387(94)00492-W

Synthesis and catalase activity of manganese(II) complexes of cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH₂): X-ray crystal structure of [Mn(η¹η¹-nda)(phen)₂]·EtOH·H₂O (phen = 1,10-phenantholine). / Devereux, Michael; Curran, Martin; McCann, Malachy et al.
In: Polyhedron, Vol. 14, No. 15-16, 08.1995, p. 2247-2253.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and catalase activity of manganese(II) complexes of cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH2)

T2 - X-ray crystal structure of [Mn(η1η1-nda)(phen)2]·EtOH·H2O (phen = 1,10-phenantholine)

AU - Devereux, Michael

AU - Curran, Martin

AU - McCann, Malachy

AU - Casey, Michael T.

AU - McKee, Vickie

PY - 1995/8

Y1 - 1995/8

N2 - Manganese(II) chloride reacts with the sodium salt of cis-5-norbornene-endo-2,3-dicarboxylix acid (ndaH2) in aqueous media to give the manganese(II) complex [Mn (nda)H2O] (1). Complex 1 reacts with 1,10-phenanthroline (phen) to give the mononuclear manganese(II) adduct [Mn(η1η1-nda)(phen)2]·EtOH·H2O (2). The X-ray crystal structure of 2 shows the manganese atom at the centre of a distorted N4O2 octahedron comprising four nitrogen atoms from two chelating phen ligands, and two oxygen atoms, one from each of the two carbohylate functions of the nda-2 ligand. Spectroscopic and magnetic data for 1 and 2 are reported, together with their catalytic activity towards the disproportionation of H2O2.

AB - Manganese(II) chloride reacts with the sodium salt of cis-5-norbornene-endo-2,3-dicarboxylix acid (ndaH2) in aqueous media to give the manganese(II) complex [Mn (nda)H2O] (1). Complex 1 reacts with 1,10-phenanthroline (phen) to give the mononuclear manganese(II) adduct [Mn(η1η1-nda)(phen)2]·EtOH·H2O (2). The X-ray crystal structure of 2 shows the manganese atom at the centre of a distorted N4O2 octahedron comprising four nitrogen atoms from two chelating phen ligands, and two oxygen atoms, one from each of the two carbohylate functions of the nda-2 ligand. Spectroscopic and magnetic data for 1 and 2 are reported, together with their catalytic activity towards the disproportionation of H2O2.

UR - https://www.scopus.com/pages/publications/4243358727

U2 - 10.1016/0277-5387(94)00492-W

DO - 10.1016/0277-5387(94)00492-W

M3 - Article

AN - SCOPUS:4243358727

SN - 0277-5387

VL - 14

SP - 2247

EP - 2253

JO - Polyhedron

JF - Polyhedron

IS - 15-16

ER -