Abstract
The synthesis of 4,6-O-benzylidene-β-D-erythro-2-3-dideoxyhex-2-enopyranosides and their osmium and ruthenium catalysed dihydroxylation reactions have been investigated. These reactions have been shown, for a range of monosaccharides and a disaccharide, to proceed stereospecifically to give β-D-allopyranosides in moderate to excellent yield.
Original language | English |
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Pages (from-to) | 327-335 |
Number of pages | 9 |
Journal | Carbohydrate Research |
Volume | 334 |
Issue number | 4 |
DOIs | |
Publication status | Published - 7 Sep 2001 |
Externally published | Yes |
Keywords
- β-D-Allopyranoside
- β-D-erythro-2, 3-Dideoxyhex-2-enopyranosides
- Dihydroxylation
- Inversion of configuration
- Stereospecific synthesis