Spirobicyclic diamines 1: synthesis of proline-derived spirolactams via thermal intramolecular ester aminolysis

Fintan Kelleher, Sinead Kelly

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

Proline-derived [4.4]-spirolactams have been synthesised in good yields by a reductive-amination reaction followed by thermal cyclisation of the resulting amine onto the proline ester group in refluxing toluene. The synthesis of the corresponding [4.5]-spirolactams by the same method gave much reduced yields.

Original languageEnglish
Pages (from-to)3005-3008
Number of pages4
JournalTetrahedron Letters
Volume47
Issue number18
DOIs
Publication statusPublished - 1 May 2006

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