Sodium-selective polymeric membrane electrodes based on calix[4]arene ionophores

Aodhmar M. Cadogan; Dermot Diamond; Malcolm R. Smyth; Mary Deasy; M. Anthony McKervey; Stephen J. Harris

doi:10.1039/AN9891401551

Sodium-selective polymeric membrane electrodes based on calix[4]arene ionophores

Aodhmar M. Cadogan, Dermot Diamond, Malcolm R. Smyth, Mary Deasy, M. Anthony McKervey, Stephen J. Harris

Research output: Contribution to journal › Article › peer-review

Abstract

Sodium-selective electrodes were prepared with polymeric membranes containing ester and ketone derivatives of p-tert-butyl calix[4]arene. The electrodes were prepared with 2-nitrophenyl octyl ether as the solvent mediator and potassium tetrakis(p-chlorophenyl)borate as the ion exchanger in a poly(vinyl chloride) matrix. Several of the ligands examined produced electrodes with near-Nernstian slopes, detection limits of ca. 10^-5 M for sodium and excellent selectivity against a range of common cations.

Original language	English
Pages (from-to)	1551-1554
Number of pages	4
Journal	Analyst
Volume	114
DOIs	https://doi.org/10.1039/AN9891401551
Publication status	Published - 1989
Externally published	Yes

Keywords

Calixarene
Ion-selective electrode
Ionophore
Phase transfer study

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10.1039/AN9891401551

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title = "Sodium-selective polymeric membrane electrodes based on calix[4]arene ionophores",

abstract = "Sodium-selective electrodes were prepared with polymeric membranes containing ester and ketone derivatives of p-tert-butyl calix[4]arene. The electrodes were prepared with 2-nitrophenyl octyl ether as the solvent mediator and potassium tetrakis(p-chlorophenyl)borate as the ion exchanger in a poly(vinyl chloride) matrix. Several of the ligands examined produced electrodes with near-Nernstian slopes, detection limits of ca. 10-5 M for sodium and excellent selectivity against a range of common cations.",

keywords = "Calixarene, Ion-selective electrode, Ionophore, Phase transfer study",

author = "Cadogan, \{Aodhmar M.\} and Dermot Diamond and Smyth, \{Malcolm R.\} and Mary Deasy and McKervey, \{M. Anthony\} and Harris, \{Stephen J.\}",

year = "1989",

doi = "10.1039/AN9891401551",

language = "English",

volume = "114",

pages = "1551--1554",

journal = "Analyst",

issn = "0003-2654",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Sodium-selective polymeric membrane electrodes based on calix[4]arene ionophores

AU - Cadogan, Aodhmar M.

AU - Diamond, Dermot

AU - Smyth, Malcolm R.

AU - Deasy, Mary

AU - McKervey, M. Anthony

AU - Harris, Stephen J.

PY - 1989

Y1 - 1989

N2 - Sodium-selective electrodes were prepared with polymeric membranes containing ester and ketone derivatives of p-tert-butyl calix[4]arene. The electrodes were prepared with 2-nitrophenyl octyl ether as the solvent mediator and potassium tetrakis(p-chlorophenyl)borate as the ion exchanger in a poly(vinyl chloride) matrix. Several of the ligands examined produced electrodes with near-Nernstian slopes, detection limits of ca. 10-5 M for sodium and excellent selectivity against a range of common cations.

AB - Sodium-selective electrodes were prepared with polymeric membranes containing ester and ketone derivatives of p-tert-butyl calix[4]arene. The electrodes were prepared with 2-nitrophenyl octyl ether as the solvent mediator and potassium tetrakis(p-chlorophenyl)borate as the ion exchanger in a poly(vinyl chloride) matrix. Several of the ligands examined produced electrodes with near-Nernstian slopes, detection limits of ca. 10-5 M for sodium and excellent selectivity against a range of common cations.

KW - Calixarene

KW - Ion-selective electrode

KW - Ionophore

KW - Phase transfer study

UR - https://www.scopus.com/pages/publications/0024946915

U2 - 10.1039/AN9891401551

DO - 10.1039/AN9891401551

M3 - Article

AN - SCOPUS:0024946915

SN - 0003-2654

VL - 114

SP - 1551

EP - 1554

JO - Analyst

JF - Analyst

ER -

Sodium-selective polymeric membrane electrodes based on calix[4]arene ionophores

Abstract

Keywords

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