Separation and photophysical properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ stereoisomers of a dinuclear ruthenium(II) complex

Wesley R. Browne; C. M. O'Connor; Claudio Villani; Johannes G. Vos

doi:10.1021/ic010473m

Separation and photophysical properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ stereoisomers of a dinuclear ruthenium(II) complex

Wesley R. Browne
, C. M. O'Connor
, Claudio Villani
, Johannes G. Vos

Research output: Contribution to journal › Article › peer-review

Abstract

The separation of the four stereoisomers of [(Ru(boy)₂)₂(bpt)](PF₆)₃ (where bpy=2,2′-bipyridine, Hbpt=3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semi-preparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.

Original language	English
Pages (from-to)	5461-5464
Number of pages	4
Journal	Inorganic Chemistry
Volume	40
Issue number	21
DOIs	https://doi.org/10.1021/ic010473m
Publication status	Published - 8 Oct 2001

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title = "Separation and photophysical properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ stereoisomers of a dinuclear ruthenium(II) complex",

abstract = "The separation of the four stereoisomers of [(Ru(boy)2)2(bpt)](PF6)3 (where bpy=2,2′-bipyridine, Hbpt=3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semi-preparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.",

author = "Browne, \{Wesley R.\} and O'Connor, \{C. M.\} and Claudio Villani and Vos, \{Johannes G.\}",

year = "2001",

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journal = "Inorganic Chemistry",

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T1 - Separation and photophysical properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ stereoisomers of a dinuclear ruthenium(II) complex

AU - Browne, Wesley R.

AU - O'Connor, C. M.

AU - Villani, Claudio

AU - Vos, Johannes G.

PY - 2001/10/8

Y1 - 2001/10/8

N2 - The separation of the four stereoisomers of [(Ru(boy)2)2(bpt)](PF6)3 (where bpy=2,2′-bipyridine, Hbpt=3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semi-preparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.

AB - The separation of the four stereoisomers of [(Ru(boy)2)2(bpt)](PF6)3 (where bpy=2,2′-bipyridine, Hbpt=3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semi-preparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.

UR - https://www.scopus.com/pages/publications/0035828877

U2 - 10.1021/ic010473m

DO - 10.1021/ic010473m

M3 - Article

C2 - 11578194

AN - SCOPUS:0035828877

SN - 0020-1669

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SP - 5461

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Separation and photophysical properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ stereoisomers of a dinuclear ruthenium(II) complex

Abstract

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