Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na+ ion: Evidence for hydronium ion complexation

Volker Böhmer; Walter Vogt; Stephen J. Harris; Raymond G. Leonard; Elizabeth M. Collins; Mary Deasy; M. Anthony McKervey; Michael Owens

doi:10.1039/p19900000431

Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na⁺ ion: Evidence for hydronium ion complexation

Volker Böhmer
, Walter Vogt
, Stephen J. Harris
, Raymond G. Leonard
, Elizabeth M. Collins
, Mary Deasy
, M. Anthony McKervey
, Michael Owens

Research output: Contribution to journal › Article › peer-review

Abstract

Calix[A]arene tetraethyl ester (1a) is hydrolysed by trifluoroacetic acid with the loss of one, and only one, ester group to form a monoacid triester; the process, which is inhibited by Na⁺ ion, is believed to involve specific hydronium ion complexation within the calixarene receptor.

Original language	English
Pages (from-to)	431-432
Number of pages	2
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	2
DOIs	https://doi.org/10.1039/p19900000431
Publication status	Published - 1990
Externally published	Yes

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10.1039/p19900000431

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Böhmer, V., Vogt, W., Harris, S. J., Leonard, R. G., Collins, E. M., Deasy, M., McKervey, M. A., & Owens, M. (1990). Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na⁺ ion: Evidence for hydronium ion complexation. Journal of the Chemical Society, Perkin Transactions 1, (2), 431-432. https://doi.org/10.1039/p19900000431

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title = "Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na+ ion: Evidence for hydronium ion complexation",

abstract = "Calix[A]arene tetraethyl ester (1a) is hydrolysed by trifluoroacetic acid with the loss of one, and only one, ester group to form a monoacid triester; the process, which is inhibited by Na+ ion, is believed to involve specific hydronium ion complexation within the calixarene receptor.",

author = "Volker B{\"o}hmer and Walter Vogt and Harris, \{Stephen J.\} and Leonard, \{Raymond G.\} and Collins, \{Elizabeth M.\} and Mary Deasy and McKervey, \{M. Anthony\} and Michael Owens",

year = "1990",

doi = "10.1039/p19900000431",

language = "English",

pages = "431--432",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

issn = "1472-7781",

publisher = "Chemical Society",

number = "2",

}

Böhmer, V, Vogt, W, Harris, SJ, Leonard, RG, Collins, EM, Deasy, M, McKervey, MA & Owens, M 1990, 'Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na⁺ ion: Evidence for hydronium ion complexation', Journal of the Chemical Society, Perkin Transactions 1, no. 2, pp. 431-432. https://doi.org/10.1039/p19900000431

Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na⁺ ion: Evidence for hydronium ion complexation. / Böhmer, Volker; Vogt, Walter; Harris, Stephen J. et al.
In: Journal of the Chemical Society, Perkin Transactions 1, No. 2, 1990, p. 431-432.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na+ ion

T2 - Evidence for hydronium ion complexation

AU - Böhmer, Volker

AU - Vogt, Walter

AU - Harris, Stephen J.

AU - Leonard, Raymond G.

AU - Collins, Elizabeth M.

AU - Deasy, Mary

AU - McKervey, M. Anthony

AU - Owens, Michael

PY - 1990

Y1 - 1990

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AB - Calix[A]arene tetraethyl ester (1a) is hydrolysed by trifluoroacetic acid with the loss of one, and only one, ester group to form a monoacid triester; the process, which is inhibited by Na+ ion, is believed to involve specific hydronium ion complexation within the calixarene receptor.

UR - https://www.scopus.com/pages/publications/37049075511

U2 - 10.1039/p19900000431

DO - 10.1039/p19900000431

M3 - Article

AN - SCOPUS:37049075511

SN - 1472-7781

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JO - Journal of the Chemical Society, Perkin Transactions 1

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IS - 2

ER -

Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na+ ion: Evidence for hydronium ion complexation

Abstract

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Selective monohydrolysis of a calix[4]arene tetraethyl ester with trifluoroacetic acid and its inhibition by Na⁺ ion: Evidence for hydronium ion complexation