Polynuclear hydroxy-bridged Structure in metallo-β-cyclodextrin complexes: A study of magnetic susceptibility versus temperature

Mary McNamara; Noel R. Russell

doi:10.1007/BF01053638

Polynuclear hydroxy-bridged Structure in metallo-β-cyclodextrin complexes: A study of magnetic susceptibility versus temperature

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Abstract

Data of the variation of magnetic susceptibility with temperature were obtained by the Gouy balance method for a series of metallo-/β-CD complexes. The results support the proposal for the presence of polynuclear hydroxy-bridged structures with interacting paramagnetic centres giving rise to an antiferromagnetic character for these complexes. In the case of the Cu(II) complex estimates of the Cu-Cu distance and the Cu-O-Cu bond angle were obtained from the data.

Original language	English
Pages (from-to)	145-154
Number of pages	10
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	13
Issue number	2
DOIs	https://doi.org/10.1007/BF01053638
Publication status	Published - Jun 1992

Keywords

binuclear
magnetic
metallo-complex
β-Cyclodextrin

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10.1007/BF01053638

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title = "Polynuclear hydroxy-bridged Structure in metallo-β-cyclodextrin complexes: A study of magnetic susceptibility versus temperature",

abstract = "Data of the variation of magnetic susceptibility with temperature were obtained by the Gouy balance method for a series of metallo-/β-CD complexes. The results support the proposal for the presence of polynuclear hydroxy-bridged structures with interacting paramagnetic centres giving rise to an antiferromagnetic character for these complexes. In the case of the Cu(II) complex estimates of the Cu-Cu distance and the Cu-O-Cu bond angle were obtained from the data.",

keywords = "binuclear, magnetic, metallo-complex, β-Cyclodextrin",

author = "Mary McNamara and Russell, {Noel R.}",

year = "1992",

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journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

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T2 - A study of magnetic susceptibility versus temperature

AU - McNamara, Mary

AU - Russell, Noel R.

PY - 1992/6

Y1 - 1992/6

N2 - Data of the variation of magnetic susceptibility with temperature were obtained by the Gouy balance method for a series of metallo-/β-CD complexes. The results support the proposal for the presence of polynuclear hydroxy-bridged structures with interacting paramagnetic centres giving rise to an antiferromagnetic character for these complexes. In the case of the Cu(II) complex estimates of the Cu-Cu distance and the Cu-O-Cu bond angle were obtained from the data.

AB - Data of the variation of magnetic susceptibility with temperature were obtained by the Gouy balance method for a series of metallo-/β-CD complexes. The results support the proposal for the presence of polynuclear hydroxy-bridged structures with interacting paramagnetic centres giving rise to an antiferromagnetic character for these complexes. In the case of the Cu(II) complex estimates of the Cu-Cu distance and the Cu-O-Cu bond angle were obtained from the data.

KW - binuclear

KW - magnetic

KW - metallo-complex

KW - β-Cyclodextrin

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U2 - 10.1007/BF01053638

DO - 10.1007/BF01053638

M3 - Article

AN - SCOPUS:0002391784

SN - 0923-0750

VL - 13

SP - 145

EP - 154

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 2

ER -

Polynuclear hydroxy-bridged Structure in metallo-β-cyclodextrin complexes: A study of magnetic susceptibility versus temperature

Abstract

Keywords

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