@inproceedings{16f3894b553241ccb6b82be1da1ad6d2,
title = "Photopolymer Material Durability and Safety in Holographic Diffusers for Visual Applications",
abstract = "This study introduces novel holographic diffuser applications employing acrylamide- or diacetone acrylamide-based photopolymers, patterned within the volume on a micron scale by a single-beam holographic recording process. These diffusers have previously been presented as potential treatments for amblyopia and diplopia. This work has now been extended to spectrometric analysis to determine their properties under broadband light. Diffusive elements with higher diffusion efficiencies exhibited a marginal reduction (< 5%) in diffusion efficiency across most of the visible spectrum. Given the intended application of these holographic diffusers, cytotoxicity assessments were also performed. This is significant as there is a difference in toxicity between the crystalline acrylamide (classified as a category 3 material) and diacetone acrylamide (classified as a category 4 material). The findings indicated substantially lower toxicity in holograms produced with diacetone acrylamide-based photopolymer. The accelerated ageing of both formulations of holographic diffusers indicated that the acrylamide-based holographic diffusers did not reduce efficacy in the 292 days of ageing. The diacetone acrylamide-based holographic diffusers exhibited reduced efficacy by day 182. Despite this, both formulations have been shown to perform for prolonged periods as the treatment modality would require. These results emphasise that holographic diffusers exhibit minimal spectral impact, and longevity on the scale of treatment regimes which are crucial considerations for their prospective use case as treatments for amblyopia and diplopia.",
keywords = "acrylamide photopolymer, cytotoxicity, diacetone acrylamide photopolymer, hologram, Holographic diffusers, holography, photopolymer ageing study",
author = "Matthew Hellis and Alan Casey and Edoardo Splendi and Suzanne Martin and Matthew Sheehan and Kevin Murphy",
note = "Publisher Copyright: {\textcopyright} 2024 SPIE.; Photosensitive Materials and their Applications III 2024 ; Conference date: 08-04-2024 Through 10-04-2024",
year = "2024",
doi = "10.1117/12.3016945",
language = "English",
series = "Proceedings of SPIE - The International Society for Optical Engineering",
publisher = "SPIE",
editor = "McLeod, {Robert R.} and Villalobos, {Inmaculada Pascual} and Yasuo Tomita",
booktitle = "Photosensitive Materials and their Applications III",
address = "United States",
}