TY - JOUR
T1 - Pencil and Gold Electrode Materials for the Electrochemical Study and Analysis of Dinitrotoluene
AU - Kurian, Kevin J.
AU - De Maere, Julie
AU - Schazmann, Benjamin
N1 - Publisher Copyright:
© 2024 The Authors. Published by American Chemical Society.
PY - 2024/2/27
Y1 - 2024/2/27
N2 - The aim of our work was to investigate practical and robust methods for the electrochemical analysis of DNT. Using gold WEs, we differentiated between the nitro substituents in 2,4- and 2,6-DNT in organic electrolyte systems. Switching to an aqueous electrolyte (2 M H2SO4), a limit of detection (LOD) of 0.158 ppm (0.87 μM) and a limit of quantitation (LOQ) of 0.48 ppm (2.64 μM) were observed for 2,4-DNT. Subsequent simplification to wooden craft pencils as WEs in aqueous 2 M H2SO4 electrolyte achieved a LOD of 4.8 ppm (26.48 μM) and a LOQ of 14.6 ppm (80.54 μM) for 2,4-DNT. Alongside this easily renewable WE choice, 2 M H2SO4 was found to improve the solubility of DNT in aqueous media and has not been previously reported as an electrolyte in DNT electroanalysis. On testing a range of pencil grades from 4H to 8B, it was found that 4B gave the best sensitivity. The work serves as a preliminary study into materials that, through their simplicity and availability, may be suitable for the development of a robust and portable instrumental method through the electrochemical work presented here.
AB - The aim of our work was to investigate practical and robust methods for the electrochemical analysis of DNT. Using gold WEs, we differentiated between the nitro substituents in 2,4- and 2,6-DNT in organic electrolyte systems. Switching to an aqueous electrolyte (2 M H2SO4), a limit of detection (LOD) of 0.158 ppm (0.87 μM) and a limit of quantitation (LOQ) of 0.48 ppm (2.64 μM) were observed for 2,4-DNT. Subsequent simplification to wooden craft pencils as WEs in aqueous 2 M H2SO4 electrolyte achieved a LOD of 4.8 ppm (26.48 μM) and a LOQ of 14.6 ppm (80.54 μM) for 2,4-DNT. Alongside this easily renewable WE choice, 2 M H2SO4 was found to improve the solubility of DNT in aqueous media and has not been previously reported as an electrolyte in DNT electroanalysis. On testing a range of pencil grades from 4H to 8B, it was found that 4B gave the best sensitivity. The work serves as a preliminary study into materials that, through their simplicity and availability, may be suitable for the development of a robust and portable instrumental method through the electrochemical work presented here.
UR - https://www.scopus.com/pages/publications/85185605614
U2 - 10.1021/acsomega.3c08741
DO - 10.1021/acsomega.3c08741
M3 - Article
AN - SCOPUS:85185605614
SN - 2470-1343
VL - 9
SP - 9375
EP - 9382
JO - ACS Omega
JF - ACS Omega
IS - 8
ER -
