Abstract
Five orthogonal smectic phases (Sm-A, Sm-Ab, Sm-APR, Sm-APAR, and Sm-APA) were observed in a 4-cyanoresorcinol bisbenzoate with two terephthalate -based wings achiral bent-core (BC) compound. The phase behavior was investigated by polarising optical microscopy, second harmonic electro-optic response (EO2) and dielectric spectroscopy. The field dependent biaxiality of polar and non-polar Sm-A phases was studied. It is obviously of enormous scientific significance and practical interest to find five different orthogonal smectic phases in a low molecular weight bent-core (BC) compound at relatively low temperatures.
| Original language | English |
|---|---|
| Pages (from-to) | 116-121 |
| Number of pages | 6 |
| Journal | Molecular Crystals and Liquid Crystals |
| Volume | 610 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 24 Mar 2015 |
Keywords
- bent-core molecule
- dielectric relaxation
- electro-optic effects
- orthogonal Smectic