Novel calixarene-Schiff bases that bind silver(I) ion

Bernadette S. Creaven; Mary Deasy; Paul M. Flood; John McGinley; Brian A. Murray

doi:10.1016/j.inoche.2008.06.011

Novel calixarene-Schiff bases that bind silver(I) ion

Bernadette S. Creaven, Mary Deasy, Paul M. Flood, John McGinley, Brian A. Murray

Research output: Contribution to journal › Article › peer-review

Abstract

Two novel calix[4]arene-Schiff base receptors have been synthesized. One of the new compounds has two pendant aldimines, while the second has been prepared by two-point attachment of a calixarene-dialdehyde onto a calixarene-diamine to form a "calix-tube". Preliminary binding studies with AgClO₄ show large complexation-induced shifts in ¹H NMR positions.

Original language	English
Pages (from-to)	1215-1220
Number of pages	6
Journal	Inorganic Chemistry Communications
Volume	11
Issue number	10
DOIs	https://doi.org/10.1016/j.inoche.2008.06.011
Publication status	Published - Oct 2008
Externally published	Yes

Keywords

Calixarenes
Complexation
Schiff base
Silver

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10.1016/j.inoche.2008.06.011

https://arrow.tudublin.ie/ittsciart/74Licence: CC BY-NC-SA

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title = "Novel calixarene-Schiff bases that bind silver(I) ion",

abstract = "Two novel calix[4]arene-Schiff base receptors have been synthesized. One of the new compounds has two pendant aldimines, while the second has been prepared by two-point attachment of a calixarene-dialdehyde onto a calixarene-diamine to form a {"}calix-tube{"}. Preliminary binding studies with AgClO4 show large complexation-induced shifts in 1H NMR positions.",

keywords = "Calixarenes, Complexation, Schiff base, Silver",

author = "Creaven, \{Bernadette S.\} and Mary Deasy and Flood, \{Paul M.\} and John McGinley and Murray, \{Brian A.\}",

note = "Funding Information: BAM and BSC acknowledge the Irish Higher Education Authority for its funding of the NCSR, including JMcG{\textquoteright}s post-doctoral fellowship. PMF thanks Enterprise Ireland, the Postgraduate R\&D Skills Programme, and ITT-Dublin{\textquoteright}s PhD Continuation Fund for grant support. ",

year = "2008",

month = oct,

doi = "10.1016/j.inoche.2008.06.011",

language = "English",

volume = "11",

pages = "1215--1220",

journal = "Inorganic Chemistry Communications",

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publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Novel calixarene-Schiff bases that bind silver(I) ion

AU - Creaven, Bernadette S.

AU - Deasy, Mary

AU - Flood, Paul M.

AU - McGinley, John

AU - Murray, Brian A.

N1 - Funding Information: BAM and BSC acknowledge the Irish Higher Education Authority for its funding of the NCSR, including JMcG’s post-doctoral fellowship. PMF thanks Enterprise Ireland, the Postgraduate R&D Skills Programme, and ITT-Dublin’s PhD Continuation Fund for grant support.

PY - 2008/10

Y1 - 2008/10

N2 - Two novel calix[4]arene-Schiff base receptors have been synthesized. One of the new compounds has two pendant aldimines, while the second has been prepared by two-point attachment of a calixarene-dialdehyde onto a calixarene-diamine to form a "calix-tube". Preliminary binding studies with AgClO4 show large complexation-induced shifts in 1H NMR positions.

AB - Two novel calix[4]arene-Schiff base receptors have been synthesized. One of the new compounds has two pendant aldimines, while the second has been prepared by two-point attachment of a calixarene-dialdehyde onto a calixarene-diamine to form a "calix-tube". Preliminary binding studies with AgClO4 show large complexation-induced shifts in 1H NMR positions.

KW - Calixarenes

KW - Complexation

KW - Schiff base

KW - Silver

UR - https://www.scopus.com/pages/publications/53149117411

U2 - 10.1016/j.inoche.2008.06.011

DO - 10.1016/j.inoche.2008.06.011

M3 - Article

AN - SCOPUS:53149117411

SN - 1387-7003

VL - 11

SP - 1215

EP - 1220

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 10

ER -

Novel calixarene-Schiff bases that bind silver(I) ion

Abstract

Keywords

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