Morphology-Directed Synthesis of LiFePO4 and LiCoPO4 from Nanostructured Li1+2 xPO3+ x

Hany El-Shinawi; Edmund J. Cussen; Serena A. Corr

doi:10.1021/acs.inorgchem.9b00517

Morphology-Directed Synthesis of LiFePO₄ and LiCoPO₄ from Nanostructured Li_{1+2 x}PO_{3+ x}

Hany El-Shinawi
, Edmund J. Cussen
, Serena A. Corr

Research output: Contribution to journal › Article › peer-review

Abstract

A LiPO₃-type nanostructure has been developed using a simple microwave approach at temperatures as low as 200 °C. This phase presents an ideal architecture for the morphology-directed synthesis of the olivine-type phases LiFePO₄ and LiCoPO₄, through a simple and scalable solution-based technique. Pure and carbon-composited olivine phases of interconnected nanoparticulate morphologies display excellent performance at high rates (up to 20 C) over 500 cycles in Li-ion battery cells.

Original language	English
Pages (from-to)	6946-6949
Number of pages	4
Journal	Inorganic Chemistry
Volume	58
Issue number	10
DOIs	https://doi.org/10.1021/acs.inorgchem.9b00517
Publication status	Published - 20 May 2019
Externally published	Yes

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10.1021/acs.inorgchem.9b00517

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title = "Morphology-Directed Synthesis of LiFePO4 and LiCoPO4 from Nanostructured Li1+2 xPO3+ x",

abstract = "A LiPO3-type nanostructure has been developed using a simple microwave approach at temperatures as low as 200 °C. This phase presents an ideal architecture for the morphology-directed synthesis of the olivine-type phases LiFePO4 and LiCoPO4, through a simple and scalable solution-based technique. Pure and carbon-composited olivine phases of interconnected nanoparticulate morphologies display excellent performance at high rates (up to 20 C) over 500 cycles in Li-ion battery cells.",

author = "Hany El-Shinawi and Cussen, \{Edmund J.\} and Corr, \{Serena A.\}",

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AU - Cussen, Edmund J.

AU - Corr, Serena A.

PY - 2019/5/20

Y1 - 2019/5/20

N2 - A LiPO3-type nanostructure has been developed using a simple microwave approach at temperatures as low as 200 °C. This phase presents an ideal architecture for the morphology-directed synthesis of the olivine-type phases LiFePO4 and LiCoPO4, through a simple and scalable solution-based technique. Pure and carbon-composited olivine phases of interconnected nanoparticulate morphologies display excellent performance at high rates (up to 20 C) over 500 cycles in Li-ion battery cells.

AB - A LiPO3-type nanostructure has been developed using a simple microwave approach at temperatures as low as 200 °C. This phase presents an ideal architecture for the morphology-directed synthesis of the olivine-type phases LiFePO4 and LiCoPO4, through a simple and scalable solution-based technique. Pure and carbon-composited olivine phases of interconnected nanoparticulate morphologies display excellent performance at high rates (up to 20 C) over 500 cycles in Li-ion battery cells.

UR - https://www.scopus.com/pages/publications/85066129930

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DO - 10.1021/acs.inorgchem.9b00517

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JO - Inorganic Chemistry

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IS - 10

ER -

Morphology-Directed Synthesis of LiFePO4 and LiCoPO4 from Nanostructured Li1+2 xPO3+ x

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Morphology-Directed Synthesis of LiFePO₄ and LiCoPO₄ from Nanostructured Li_{1+2 x}PO_{3+ x}