Molecular-salt hybrids; Integration of ammonia borane into lithium halides

Irene Cascallana-Matías; Joachim Breternitz; Annabelle Baker; Hallam Davis; Edmund J. Cussen; Duncan H. Gregory

doi:10.1039/c9qi00099b

Molecular-salt hybrids; Integration of ammonia borane into lithium halides

Irene Cascallana-Matías
, Joachim Breternitz
, Annabelle Baker
, Hallam Davis
, Edmund J. Cussen
, Duncan H. Gregory

Research output: Contribution to journal › Article › peer-review

Abstract

New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH₃BH₃) and [LiI](NH₃BH₃)₂ are members of a generic [LiX]_m(AB)_n (X = I^-, BH₄^-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li⁺-ion conductivity more than two orders of magnitude higher than either LiBH₄ or LiI.

Original language	English
Pages (from-to)	808-812
Number of pages	5
Journal	Inorganic Chemistry Frontiers
Volume	6
Issue number	3
DOIs	https://doi.org/10.1039/c9qi00099b
Publication status	Published - Mar 2019
Externally published	Yes

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title = "Molecular-salt hybrids; Integration of ammonia borane into lithium halides",

abstract = "New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.",

author = "Irene Cascallana-Mat{\'i}as and Joachim Breternitz and Annabelle Baker and Hallam Davis and Cussen, \{Edmund J.\} and Gregory, \{Duncan H.\}",

note = "Publisher Copyright: {\textcopyright} 2019 the Partner Organisations.",

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AU - Cascallana-Matías, Irene

AU - Breternitz, Joachim

AU - Baker, Annabelle

AU - Davis, Hallam

AU - Cussen, Edmund J.

AU - Gregory, Duncan H.

PY - 2019/3

Y1 - 2019/3

N2 - New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

AB - New molecular-salt-like hybrids contain ammonia borane (AB) in co-existence with lithium halides in single lattices. [LiI](NH3BH3) and [LiI](NH3BH3)2 are members of a generic [LiX]m(AB)n (X = I-, BH4-; m, n = integer) materials family which release hydrogen on decomposition and demonstrate Li+-ion conductivity more than two orders of magnitude higher than either LiBH4 or LiI.

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U2 - 10.1039/c9qi00099b

DO - 10.1039/c9qi00099b

M3 - Article

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JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

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ER -

Molecular-salt hybrids; Integration of ammonia borane into lithium halides

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