Hexakis-(prop-2-enamide)-copper(II) bis(perchlorate) and hexakis(prop-2-enamide)-manganese(II) bis-(per-chlorate)

Andrew Kellett; Georgina Rosair; Michael Devereux; Mary McNamara; Malachy McCann

doi:10.1107/S0108270110038813

Hexakis-(prop-2-enamide)-copper(II) bis(perchlorate) and hexakis(prop-2-enamide)-manganese(II) bis-(per-chlorate)

Andrew Kellett
, Georgina Rosair
, Michael Devereux
, Mary McNamara
, Malachy McCann

Research output: Contribution to journal › Article › peer-review

Abstract

The structures of [Cu(AA)₆](ClO₄)₂, (I), and [Mn(AA)₆](ClO₄)₂, (II) (AA is acryl-amide, also known as prop-2-en-amide; C₃H₅NO), display both intra- and inter-molecular N-H⋯O hydrogen bonding. A three-dimensional network is propagated via the perchlorate counter-ions. There are two crystallographically independent mol-ecules in the copper complex, with the most significant difference between them being the conformation of one symmetry-related pair of AA ligands which are in the unusual syn conformation. The copper complex exhibits syn/anti disorder of the =CH₂ group in one pair of symmetry-related AA ligands. The Cu^II and Mn^II centres are both situated on centres of inversion. The copper complex cation has octa-hedral coordination geometry with typical Jahn-Teller distortions.

Original language	English
Pages (from-to)	m358-m362
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	66
Issue number	11
DOIs	https://doi.org/10.1107/S0108270110038813
Publication status	Published - Nov 2010

Access to Document

10.1107/S0108270110038813

https://arrow.tudublin.ie/materart/1Licence: CC BY-NC-SA

Cite this

@article{b2f4fd0055654136b12831f73ad1c821,

title = "Hexakis-(prop-2-enamide)-copper(II) bis(perchlorate) and hexakis(prop-2-enamide)-manganese(II) bis-(per-chlorate)",

abstract = "The structures of [Cu(AA)6](ClO4)2, (I), and [Mn(AA)6](ClO4)2, (II) (AA is acryl-amide, also known as prop-2-en-amide; C3H5NO), display both intra- and inter-molecular N-H⋯O hydrogen bonding. A three-dimensional network is propagated via the perchlorate counter-ions. There are two crystallographically independent mol-ecules in the copper complex, with the most significant difference between them being the conformation of one symmetry-related pair of AA ligands which are in the unusual syn conformation. The copper complex exhibits syn/anti disorder of the =CH2 group in one pair of symmetry-related AA ligands. The CuII and MnII centres are both situated on centres of inversion. The copper complex cation has octa-hedral coordination geometry with typical Jahn-Teller distortions.",

author = "Andrew Kellett and Georgina Rosair and Michael Devereux and Mary McNamara and Malachy McCann",

year = "2010",

month = nov,

doi = "10.1107/S0108270110038813",

language = "English",

volume = "66",

pages = "m358--m362",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - Hexakis-(prop-2-enamide)-copper(II) bis(perchlorate) and hexakis(prop-2-enamide)-manganese(II) bis-(per-chlorate)

AU - Kellett, Andrew

AU - Rosair, Georgina

AU - Devereux, Michael

AU - McNamara, Mary

AU - McCann, Malachy

PY - 2010/11

Y1 - 2010/11

N2 - The structures of [Cu(AA)6](ClO4)2, (I), and [Mn(AA)6](ClO4)2, (II) (AA is acryl-amide, also known as prop-2-en-amide; C3H5NO), display both intra- and inter-molecular N-H⋯O hydrogen bonding. A three-dimensional network is propagated via the perchlorate counter-ions. There are two crystallographically independent mol-ecules in the copper complex, with the most significant difference between them being the conformation of one symmetry-related pair of AA ligands which are in the unusual syn conformation. The copper complex exhibits syn/anti disorder of the =CH2 group in one pair of symmetry-related AA ligands. The CuII and MnII centres are both situated on centres of inversion. The copper complex cation has octa-hedral coordination geometry with typical Jahn-Teller distortions.

AB - The structures of [Cu(AA)6](ClO4)2, (I), and [Mn(AA)6](ClO4)2, (II) (AA is acryl-amide, also known as prop-2-en-amide; C3H5NO), display both intra- and inter-molecular N-H⋯O hydrogen bonding. A three-dimensional network is propagated via the perchlorate counter-ions. There are two crystallographically independent mol-ecules in the copper complex, with the most significant difference between them being the conformation of one symmetry-related pair of AA ligands which are in the unusual syn conformation. The copper complex exhibits syn/anti disorder of the =CH2 group in one pair of symmetry-related AA ligands. The CuII and MnII centres are both situated on centres of inversion. The copper complex cation has octa-hedral coordination geometry with typical Jahn-Teller distortions.

UR - https://www.scopus.com/pages/publications/78349277574

U2 - 10.1107/S0108270110038813

DO - 10.1107/S0108270110038813

M3 - Article

C2 - 21051817

AN - SCOPUS:78349277574

SN - 0108-2701

VL - 66

SP - m358-m362

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

Hexakis-(prop-2-enamide)-copper(II) bis(perchlorate) and hexakis(prop-2-enamide)-manganese(II) bis-(per-chlorate)

Abstract

Access to Document

Fingerprint

Cite this