Effect of pH Value on the Bandgap Energy and Particles Size for Biosynthesis of ZnO Nanoparticles: Efficiency for Photocatalytic Adsorption of Methyl Orange

Bachir Gherbi, Salah Eddine Laouini, Souhaila Meneceur, Abderrhmane Bouafia, Hadia Hemmami, Mohammed Laid Tedjani, Gobika Thiripuranathar, Ahmed Barhoum, Farid Menaa

Research output: Contribution to journalArticlepeer-review

Abstract

In this paper, ZnO nanoparticles (NPs) were greenly synthesized at different pH values of 4, 6, 9.5, and 11 via Portulaca oleracea leaf extract, and the effect of pH on the optical and structural properties was studied. UV-Vis spectrophotometers and FTIR spectroscopy characterized the optical properties. Meanwhile, the structural properties were characterized via Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). Furthermore, their photocatalytic dye degradation was examined against methyl orange dye. The characterization results have confirmed the successful biosynthesis of ZnO nanoparticles with a size ranging between 22.17 to 27.38 nm. The synthesis pH value significantly influenced ZnO NPs’ optical and morphological properties. The results have also indicated the high performance of the greenly synthesized ZnO NPs for dye degradation.

Original languageEnglish
Article number11300
JournalSustainability (Switzerland)
Volume14
Issue number18
DOIs
Publication statusPublished - Sep 2022

Keywords

  • green synthesis
  • metallic nanoparticles
  • methyl orange
  • photocatalysis
  • Portulaca oleracea
  • sustainability
  • zinc oxide

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