Copper(II) complexes of heptanedioic acid (hdaH2) and octanedioic acid (odaH2): X-ray crystal structures OF [Cu(η2-hda)(phen)2]·11.73H2O and [Cu(η2-oda)(phen)2]·12H2O (phen = 1,10-Phenanthroline)

Malachy McCann; James F. Cronin; Michael Devereux; George Ferguson

doi:10.1016/0277-5387(95)00075-4

Copper(II) complexes of heptanedioic acid (hdaH₂) and octanedioic acid (odaH₂): X-ray crystal structures OF [Cu(η²-hda)(phen)₂]·11.73H₂O and [Cu(η²-oda)(phen)₂]·12H₂O (phen = 1,10-Phenanthroline)

Malachy McCann
, James F. Cronin
, Michael Devereux
, George Ferguson

VP Research and Innovation

Research output: Contribution to journal › Article › peer-review

Abstract

The α,ω-dicarboxylic acids heptanedioic acid (hdaH₂) and octanedioic acid (odaH₂) reacted smoothly with [Cu₂(μ-O₂CCH₃)₄(H₂O)₂] in water giving the insoluble copper(II) complexes [Cu(hda)] (1) and [Cu(oda)] (2). Complexes 1 and 2 reacted further with 1,10-phenanthroline (phen) giving [Cu(η²-hda)(phen)₂]·xH₂O and [Cu(η²-oda) (phen)₂]·xH₂O (x²8), respectively. The X-ray crystal structures of [Cu(η²-hda) (phen)₂]·11.73H₂O (3) and [Cu(η²-oda)(phen(₂]·12H₂O (4) (i.e. x = 11.73 and 12, respectively) reveal that, for each complex, the copper(II) atom is at the centre of a distorted octahedron comprising four nitrogen atoms from two chelating phen ligands and two oxygen atoms from a single asymmetric chelating carboxylate function, with the remaining carboxylate group of the diacid uncoordinated.

Original language	English
Pages (from-to)	2379-2387
Number of pages	9
Journal	Polyhedron
Volume	14
Issue number	17-18
DOIs	https://doi.org/10.1016/0277-5387(95)00075-4
Publication status	Published - Aug 1995

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@article{da3202e726ed452ea031752f0473b518,

title = "Copper(II) complexes of heptanedioic acid (hdaH2) and octanedioic acid (odaH2): X-ray crystal structures OF [Cu(η2-hda)(phen)2]·11.73H2O and [Cu(η2-oda)(phen)2]·12H2O (phen = 1,10-Phenanthroline)",

abstract = "The α,ω-dicarboxylic acids heptanedioic acid (hdaH2) and octanedioic acid (odaH2) reacted smoothly with [Cu2(μ-O2CCH3)4(H2O)2] in water giving the insoluble copper(II) complexes [Cu(hda)] (1) and [Cu(oda)] (2). Complexes 1 and 2 reacted further with 1,10-phenanthroline (phen) giving [Cu(η2-hda)(phen)2]·xH2O and [Cu(η2-oda) (phen)2]·xH2O (x28), respectively. The X-ray crystal structures of [Cu(η2-hda) (phen)2]·11.73H2O (3) and [Cu(η2-oda)(phen(2]·12H2O (4) (i.e. x = 11.73 and 12, respectively) reveal that, for each complex, the copper(II) atom is at the centre of a distorted octahedron comprising four nitrogen atoms from two chelating phen ligands and two oxygen atoms from a single asymmetric chelating carboxylate function, with the remaining carboxylate group of the diacid uncoordinated.",

author = "Malachy McCann and Cronin, \{James F.\} and Michael Devereux and George Ferguson",

year = "1995",

month = aug,

doi = "10.1016/0277-5387(95)00075-4",

language = "English",

volume = "14",

pages = "2379--2387",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "17-18",

}

Copper(II) complexes of heptanedioic acid (hdaH₂) and octanedioic acid (odaH₂): X-ray crystal structures OF [Cu(η²-hda)(phen)₂]·11.73H₂O and [Cu(η²-oda)(phen)₂]·12H₂O (phen = 1,10-Phenanthroline). / McCann, Malachy; Cronin, James F.; Devereux, Michael et al.
In: Polyhedron, Vol. 14, No. 17-18, 08.1995, p. 2379-2387.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Copper(II) complexes of heptanedioic acid (hdaH2) and octanedioic acid (odaH2)

T2 - X-ray crystal structures OF [Cu(η2-hda)(phen)2]·11.73H2O and [Cu(η2-oda)(phen)2]·12H2O (phen = 1,10-Phenanthroline)

AU - McCann, Malachy

AU - Cronin, James F.

AU - Devereux, Michael

AU - Ferguson, George

PY - 1995/8

Y1 - 1995/8

N2 - The α,ω-dicarboxylic acids heptanedioic acid (hdaH2) and octanedioic acid (odaH2) reacted smoothly with [Cu2(μ-O2CCH3)4(H2O)2] in water giving the insoluble copper(II) complexes [Cu(hda)] (1) and [Cu(oda)] (2). Complexes 1 and 2 reacted further with 1,10-phenanthroline (phen) giving [Cu(η2-hda)(phen)2]·xH2O and [Cu(η2-oda) (phen)2]·xH2O (x28), respectively. The X-ray crystal structures of [Cu(η2-hda) (phen)2]·11.73H2O (3) and [Cu(η2-oda)(phen(2]·12H2O (4) (i.e. x = 11.73 and 12, respectively) reveal that, for each complex, the copper(II) atom is at the centre of a distorted octahedron comprising four nitrogen atoms from two chelating phen ligands and two oxygen atoms from a single asymmetric chelating carboxylate function, with the remaining carboxylate group of the diacid uncoordinated.

AB - The α,ω-dicarboxylic acids heptanedioic acid (hdaH2) and octanedioic acid (odaH2) reacted smoothly with [Cu2(μ-O2CCH3)4(H2O)2] in water giving the insoluble copper(II) complexes [Cu(hda)] (1) and [Cu(oda)] (2). Complexes 1 and 2 reacted further with 1,10-phenanthroline (phen) giving [Cu(η2-hda)(phen)2]·xH2O and [Cu(η2-oda) (phen)2]·xH2O (x28), respectively. The X-ray crystal structures of [Cu(η2-hda) (phen)2]·11.73H2O (3) and [Cu(η2-oda)(phen(2]·12H2O (4) (i.e. x = 11.73 and 12, respectively) reveal that, for each complex, the copper(II) atom is at the centre of a distorted octahedron comprising four nitrogen atoms from two chelating phen ligands and two oxygen atoms from a single asymmetric chelating carboxylate function, with the remaining carboxylate group of the diacid uncoordinated.

UR - https://www.scopus.com/pages/publications/58149363819

U2 - 10.1016/0277-5387(95)00075-4

DO - 10.1016/0277-5387(95)00075-4

M3 - Article

AN - SCOPUS:58149363819

SN - 0277-5387

VL - 14

SP - 2379

EP - 2387

JO - Polyhedron

JF - Polyhedron

IS - 17-18

ER -

Copper(II) complexes of heptanedioic acid (hdaH2) and octanedioic acid (odaH2): X-ray crystal structures OF [Cu(η2-hda)(phen)2]·11.73H2O and [Cu(η2-oda)(phen)2]·12H2O (phen = 1,10-Phenanthroline)

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Copper(II) complexes of heptanedioic acid (hdaH₂) and octanedioic acid (odaH₂): X-ray crystal structures OF [Cu(η²-hda)(phen)₂]·11.73H₂O and [Cu(η²-oda)(phen)₂]·12H₂O (phen = 1,10-Phenanthroline)