Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

Bernadette S. Creaven; Mary F. Mahon; John McGinley; Ann Marie Moore

doi:10.1016/j.inoche.2005.11.008

Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

Bernadette S. Creaven
, Mary F. Mahon
, John McGinley
, Ann Marie Moore

Research output: Contribution to journal › Article › peer-review

Abstract

The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4- methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom.

Original language	English
Pages (from-to)	231-234
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	9
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2005.11.008
Publication status	Published - Feb 2006

Keywords

Copper(II) complex
Synthesis
Tridentate pyridine-amine ligand
X-ray crystal structure

Access to Document

10.1016/j.inoche.2005.11.008

Cite this

@article{fa29b8fb12d64d2ea9e90fafd88f0bb3,

title = "Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction",

abstract = "The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4- methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom.",

keywords = "Copper(II) complex, Synthesis, Tridentate pyridine-amine ligand, X-ray crystal structure",

author = "Creaven, \{Bernadette S.\} and Mahon, \{Mary F.\} and John McGinley and Moore, \{Ann Marie\}",

year = "2006",

month = feb,

doi = "10.1016/j.inoche.2005.11.008",

language = "English",

volume = "9",

pages = "231--234",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

AU - Creaven, Bernadette S.

AU - Mahon, Mary F.

AU - McGinley, John

AU - Moore, Ann Marie

PY - 2006/2

Y1 - 2006/2

N2 - The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4- methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom.

AB - The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4- methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom.

KW - Copper(II) complex

KW - Synthesis

KW - Tridentate pyridine-amine ligand

KW - X-ray crystal structure

UR - https://www.scopus.com/pages/publications/31344464431

U2 - 10.1016/j.inoche.2005.11.008

DO - 10.1016/j.inoche.2005.11.008

M3 - Article

AN - SCOPUS:31344464431

SN - 1387-7003

VL - 9

SP - 231

EP - 234

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 2

ER -

Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

Abstract

Keywords

Access to Document

Fingerprint

Cite this