TY - JOUR
T1 - A study of the thermal and photochemical reactions of the group 6 metal carbonyls with organic polymer supports
AU - Creaven, Bernadette S.
AU - Long, Conor
AU - Russell, Graham
AU - Hamilton, Julia
AU - McQuillan, Geoffrey P.
PY - 1988/6/1
Y1 - 1988/6/1
N2 - The synthesis of organic polymers containing metal carbonyl moieties is described. The reaction of [Mo(CO)4(bipy)] with poly-4-vinylpyridine proceeds smoothly to give [Mo(CO)3(bipy)(poly-4-vinylpyridine)] which has a fac configuration. The thermal chemistry of a variety of polymer-bound metal carbonyl compounds is also presented, as is evidence for the formation of [W(CO)4(poly-4-vinylpyridinestyrene)] from [W(CO)5(poly-4-vinylpyridinestyrene)]. Included is evidence for the decarbonylation of polymer-bound metal compounds resulting in polymers which contain fully decarbonylated metal centres. Preliminary photochemical investigations indicate the generation of active coordinatively unsaturated metal carbonyl species in polymer matrices at low temperatures.
AB - The synthesis of organic polymers containing metal carbonyl moieties is described. The reaction of [Mo(CO)4(bipy)] with poly-4-vinylpyridine proceeds smoothly to give [Mo(CO)3(bipy)(poly-4-vinylpyridine)] which has a fac configuration. The thermal chemistry of a variety of polymer-bound metal carbonyl compounds is also presented, as is evidence for the formation of [W(CO)4(poly-4-vinylpyridinestyrene)] from [W(CO)5(poly-4-vinylpyridinestyrene)]. Included is evidence for the decarbonylation of polymer-bound metal compounds resulting in polymers which contain fully decarbonylated metal centres. Preliminary photochemical investigations indicate the generation of active coordinatively unsaturated metal carbonyl species in polymer matrices at low temperatures.
UR - http://www.scopus.com/inward/record.url?scp=33744980695&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)80023-7
DO - 10.1016/S0020-1693(00)80023-7
M3 - Article
AN - SCOPUS:33744980695
SN - 0020-1693
VL - 146
SP - 25
EP - 31
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -